Naphthidines and O-dianisidine as redox indicators in titrations with n-bromosuccinimide

Sanke Gowda, H. and Shakunthala, R. and Subrahmanya, U. (1979) Naphthidines and O-dianisidine as redox indicators in titrations with n-bromosuccinimide. The analyst, 104 (1242). pp. 865-872. ISSN 0003-2654

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Abstract

The optimum conditions for the successful use of naphthidine, 3,3′-dimethylnaphthidine, 3,3′-dimethylnaphthidinedisulphonic acid and o-dianisidine as indicators in macro- and micro-titrations of hexacyanoferrate(II), iron(II), hydroquinone, metol and ascorbic acid with N-bromosuccinimide have been established. The indicators give a very sharp reversible colour change at the equivalence point and have advantages over the existing redox indicators. Hydrazinium sulphate and hydroxylammonium chloride have been determined indirectly. Anhydrous hexacyanoferrate(II) and iron(II) are suggested for the standardisation of N-bromosuccinimide solutions.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: Dhruva Kumar
Date Deposited: 27 May 2021 06:33
Last Modified: 27 May 2021 06:33
URI: http://eprints.uni-mysore.ac.in/id/eprint/13901

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