Mahadevappa, D. S. and Rangappa, K. S. and Made Gowda, N. M. (1980) Kinetic and mechanistic studies on the oxidation of arginine and histidine by chloramine-T in hydrochloric acid medium. Reaction kinetics and catalysis letters, 15 (1). pp. 13-19. ISSN 0133-1736
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The oxidation of amino acids by chloramine-T (CAT) in HCl medium at 30°C indicates simultaneous catalysis by H+ and Cl- ions in the HCl concentration range of 0.04-0.12 M. The reaction is first order with respect to concentrations CAT, H+ and arginine, but zero order with respect to histidine. The rate depends also on Cl- concentration following 0.7th order. At HCl concentrations \>0.12 M, the rate equation is:w=kCAT amino acid0.6 and is independent of the Cl-. A suitable mechanism has been suggested. © 1980 Akadémiai Kiadó.
| Item Type: | Article |
|---|---|
| Additional Information: | Publisher: Kluwer Academic Publishers |
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Dhruva Kumar |
| Date Deposited: | 10 Jun 2021 07:37 |
| Last Modified: | 06 Jul 2022 07:49 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/13859 |
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