Ananda Murthy, A. S. and Ananda Murthy, S. and Mahadevappa, D. S. (1989) Oxidation of thiols by sodium N-haloarylsulfonamides. Talanta, 36. p. 1051.
Full text not available from this repository. (Request a copy)Abstract
The methods for direct titration of thiols with N-halorylsulfonamides in the presence of KI were evaluated by studying the oxidation of 2-mercaptobenzoic acid, 2-mercaptopropionic acid, 3-mercaptopropionic acid, 2-naphthyl mercaptan, 2-mercaptoethanol, mercaptosuccinic acid, thiophenol, p-chlorothiophenol, Bu mercaptan, and monothioglycerol, with chloramine-T (CAT), bromamine-T (BAT) and bromamine-B (BAB). The optimum conditions were established. The precision was poorer for titrations with CAT. BAB gave better precision and accuracy for the determination of all ten thiols studied, and is recommended for use.
| Item Type: | Article |
|---|---|
| Uncontrolled Keywords: | bromamine B titrant thiol, bromamine T titrant thiol, chloramine T titrant thiol, haloarylsulfonamide titrant thiol oxidation iodide present, thiol determination redox titration |
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | Dhruva Kumar |
| Date Deposited: | 04 May 2021 15:49 |
| Last Modified: | 04 May 2021 15:49 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/13149 |
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