(3-Chloro-prop-yl)triphenyl-phospho-nium bromide

Kavitha, C. N. and Yathirajan, H. S. and Dayananda, A. S. and Gerber, T. and Hosten, Eric and Betz, Richard (2012) (3-Chloro-prop-yl)triphenyl-phospho-nium bromide. Acta crystallographica. Section E, Structure reports online, 68 (Pt 11,). ISSN 1600-5368

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Official URL: http://dx.doi.org/10.1107%2FS1600536812042122


The title compound, C(21)H(21)ClP(+)Br(-), is the bromide salt of a mixed aryl-alkyl phospho-nium cation. C-P-C angles span a range of 107.20 (10)-111.18 (10)°. The non-H atoms of the 3-chloro-propyl group adopt a staggered conformation [C-C-C-Cl torsion angle: -72.0 (3)°]. In the crystal, C-H(midline ellipsis)Br contacts connect the entities of the title compound into a double zigzag chain along b. These chains are linked into a supra-molecular layer lying parallel to (10-1) by C-H(midline ellipsis)π inter-actions.[on SciFinder (R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 2012/// [EPrints field already has value set] JA - Acta Crystallogr Sect E Struct Rep Online [Field not mapped to EPrints]
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Kodandarama
Date Deposited: 27 Jun 2013 05:59
Last Modified: 23 Nov 2015 09:02
URI: http://eprints.uni-mysore.ac.in/id/eprint/13138

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