Synthesis and characterization of complexes of non-transition elements.

Ramappa, P. G. and Nagarajappa, K. C. (1994) Synthesis and characterization of complexes of non-transition elements. Asian Journal of Chemistry, 6 (4, Cop). pp. 991-4. ISSN 0970-7077

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Abstract

New complexes of Bi and Sn prepd. from promethazine hydrochloride (PH), prochlorperazine dimaleate (PCPM) and isopropamide hydrochloride (IPPH) were characterized by cond., spectroscopic and elemental analyses. The conductometric measurements in DMF, DMSO and MeCN soln. indicate their nonelectrolyte nature. TGA data show that Bi(III) complexes are thermally stable up to 135° whereas Sn(II) complexes are thermally stable up to 230°. The ligands behave as bidentate in all these complexes. The Bi(III) complexes are assigned octahedral structure while Sn(II) complexes square-planar geometry. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 1994/// [EPrints field already has value set] JA - Asian J. Chem. [Field not mapped to EPrints]
Uncontrolled Keywords: bismuth prochlorperazine dimaleate promethazine isopropamide complex, tin prochlorperazine dimaleate promethazine isopropamide complex, prochlorperazine dimaleate bismuth tin complex, promethazine bismuth tin complex, isopropamide bismuth tin complex, thermal decompn bismuth tin complex
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Praveen Kumari B.L
Date Deposited: 24 May 2013 05:16
Last Modified: 24 May 2013 05:17
URI: http://eprints.uni-mysore.ac.in/id/eprint/10257

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