The O-Na Interaction and Octahedral Geometry around Sodium Moiety in Sodium Salt of N-bromo-4-methylbenzenesulphonamide

Yathirajan, H. S. and Rangappa, K. S. and Nagendra, P. and Mohana, K. N. (2001) The O-Na Interaction and Octahedral Geometry around Sodium Moiety in Sodium Salt of N-bromo-4-methylbenzenesulphonamide. Asian Journal of Chemistry, 13 (1). pp. 35-42. ISSN 0975-427X

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Abstract

The diverse nature of aromatic sulphonyl haloamines is due to their ability to act as sources of halonium cations, hypohalite species and N-anions which act as both bases and nucleophiles. As a result, these reagents react with a wide range of functional groups effecting an array of molecular transformations. Broma mine—T (BAT) or sodium salt of N-bromo-4-methylbenzenesulphonamide isextensively used as a brominating/oxidising agent in synthetic organic chemistry and reaction kinetics. Also, BAT is widely used in the analytical determination of various organic and inorganic substrates. The crystal and molecular structure studies of chloramine-T (CAT) 1, chloramine-B (CAB) 2, bromamine-B (BAB) 3, dibromamine—B (DBB) 3, dichloramine-T (DCT) 3, dichloramine-B (DCB) 3 and dibromamine-T (DBT) 4 have already been reported. Recently, we have reported the photolysis of BATS.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 17 Dec 2019 07:26
Last Modified: 17 Dec 2019 07:26
URI: http://eprints.uni-mysore.ac.in/id/eprint/10241

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