Do C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions help to stabilize a non-centrosymmetric structure for racemic 2,3-dibromo-1,3-diphenylpropan-1-one?

Harrison, William T. A. and Yathirajan, H. S. and Sarojini, B. K. and Narayana, B. and Anilkumar, H. G. (2005) Do C-H center dot center dot center dot O and C-H center dot center dot center dot pi interactions help to stabilize a non-centrosymmetric structure for racemic 2,3-dibromo-1,3-diphenylpropan-1-one? Acta Crystallographica Section C, Crystal Structure Communications, 61 (61). ISSN 0108-2701

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Official URL: https://dx.doi.org/10.1107/S0108270105036942

Abstract

The racemic title compound, C15H12Br2O, crystallizes in a non-centrosymmetric structure and displays a significant nonlinear optical response to red light. The crystal packing is influenced by C - H center dot center dot center dot O and C - H center dot center dot center dot pi interactions. One of the former bonds has a short H center dot center dot center dot O separation of 2.27 angstrom.

Item Type: Article
Uncontrolled Keywords: Nonlinear-Optical Materials, Crystal-Structure
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: MUL SWAPNA user
Date Deposited: 17 Dec 2019 05:54
Last Modified: 17 Dec 2019 05:54
URI: http://eprints.uni-mysore.ac.in/id/eprint/10234

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