Jasinski, Jerry P. and Butcher, Ray J. and Hakim Al-Arique, Q. N. M. and Yathirajan, H. S. and Narayana, B. (2010) N-(5-Amino-2-methyl­phen­yl)-4-(3-pyri­dyl)­pyrimidin-2-amine. Acta Crystallographica Section E, 66 (2). o349. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S1600536810000899


The title compound, C16H15N5, crystallizes with two independent mol­ecules (A and B) in the asymmetric unit. The dihedral angles of the pyrimidine ring with the benzene and pyridyl rings are 22.3 (1) and 53.2 (9)°, respectively, in mol­ecule A, and 6.8 (1) and 11.6 (9)° in mol­ecule B. The crystal packing is influenced by the collective action of weak inter­molecular N—H⋯N hydrogen bonds, a π–π stacking inter­action between neighbouring pyridyl rings of mol­ecule A [centroid–centroid distance = 3.8395 (10) Å] and C—H⋯π inter­actions.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: C Swapna Library Assistant
Date Deposited: 09 Dec 2019 09:56
Last Modified: 09 Dec 2019 09:56
URI: http://eprints.uni-mysore.ac.in/id/eprint/10173

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