Kinetics of oxidation of acetaldehyde by chloramine-T in acid medium.

Mahadevappa, D. S. and Jadhav, M. B. and Naidu, H. M. K. (1981) Kinetics of oxidation of acetaldehyde by chloramine-T in acid medium. Journal of the Indian Chemical Society, 58 (5, Cop). pp. 454-5. ISSN 0019-4522

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Abstract

The kinetics of oxidn. of acetaldehyde by chloramine-T (I) in HCl, HClO4 and H2SO4 media shows a 1st order dependence each on oxidant, substrate and [H+] ion concns., but the rate law reduces to rate = k [I] at higher aldehyde and hydrogen ion concns. A mechanism in terms of a slow interaction between N-chlorotoluenesulfonamide and the aldehyde mol. is proposed. [on SciFinder(R)]

Item Type: Article
Additional Information: Unmapped bibliographic data: PY - 1981/// [EPrints field already has value set] JA - J. Indian Chem. Soc. [Field not mapped to EPrints]
Uncontrolled Keywords: oxidn acetaldehyde chloramine T kinetics
Subjects: Physical Sciences > Chemistry
Divisions: PG Campuses > Manasagangotri, Mysore > Chemistry
Depositing User: Dhruvakumar
Date Deposited: 22 May 2013 05:11
Last Modified: 22 May 2013 05:11
URI: http://eprints.uni-mysore.ac.in/id/eprint/10125

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