Prakasha, G. and Jasinski, Jerry P. and Brown, J. S. and Yathirajan, H. S. and Ravishankara, D. K. (2013) 2-[(2-Chlorophenyl)(hydroxy)methyl]phenol. Acta Crystallographica Section E, 69 (8). o1240. ISSN 2056-9890
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Abstract
In the title compound, C13H11ClO2, the dihedral angle between the mean planes of the 2-chlorophenyl and phenol rings is 87.4 (9)°. The methyl hydroxy group lies nearly perpendicular to the plane of its attached benzene ring [O—C—C—C torsion angle = 84.3 (3)°]. The two hydroxy groups lie on the same side of the molecule and are in a slightly twisted gauche conformation [O—C—C—O torsion angle = 77.1 (8)°] to each other. In the crystal, O—H⋯O hydrogen bonds between nearby methylhydroxy groups form dimers in alternating pairs aligned diagonally along the b axis. A view along the c axis reveals a hexameric aggregate mediated by a ring of six O—H⋯O hydrogen bonds generating an R66(12) motif loop.
| Item Type: | Article |
|---|---|
| Subjects: | C Chemical Science > Chemistry |
| Divisions: | Department of > Chemistry |
| Depositing User: | C Swapna Library Assistant |
| Date Deposited: | 13 Nov 2019 06:12 |
| Last Modified: | 19 Jul 2022 11:13 |
| URI: | http://eprints.uni-mysore.ac.in/id/eprint/10009 |
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