Kaur, Manpreet and Jasinski, Jerry P. and Yathirajan, H. S. and Narayana, B. and Byrappa, K. (2014) N-(1,5-Di­methyl-3-oxo-2-phenyl-2,3-di­hydro-1H-pyrazol-4-yl)-2-(4-nitro­phen­yl)acetamide. Acta Crystallographica Section E, 70 (6). o636-o637. ISSN 2056-9890

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Official URL: https://doi.org/10.1107/S1600536814009738


In the title compound, C19H18N4O4, the nitro­phenyl and phenyl rings are twisted by 67.0 (6) and 37.4 (4)°, respectively, with respect to the pyrazole ring plane [maximum deviation = 0.0042 (16) Å]. The dihedral angle between the mean planes of the phenyl rings is 59.3 (3)°. The amide group, with a C—N—C—C torsion angle of 177.54 (13)°, is twisted away from the plane of the pyrazole ring in an anti­periplanar conformation. In the crystal, N—H⋯O hydrogen bonds involving the carbonyl group on the pyrazole ring and the amide group, together with weak C—H⋯O inter­actions forming R22(10) graph-set motifs, link the mol­ecules into chains along [100]. Additional weak C—H⋯O inter­actions involving the nitro­phenyl rings further link the mol­ecules along [001], also forming R22(10) graph-set motifs, thereby generating (010) layers.

Item Type: Article
Subjects: C Chemical Science > Chemistry
Divisions: Department of > Chemistry
Depositing User: MUL SWAPNA user
Date Deposited: 13 Nov 2019 05:52
Last Modified: 13 Nov 2019 05:52
URI: http://eprints.uni-mysore.ac.in/id/eprint/10001

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